: Joshua Pelleg
: Mechanical Properties of Silicon Based Compounds: Silicides
: Springer-Verlag
: 9783030225988
: 1
: CHF 85.50
:
: Maschinenbau, Fertigungstechnik
: English
: 286
: Wasserzeichen/DRM
: PC/MAC/eReader/Tablet
: PDF
This book focuses on the mechanical properties of silicides for very large scale integration (VLSI) applications. It presents the fabrication process for bulk silicides and thin films, and list complete testing deformation for a variety of silicon based compounds. The author also presents dislocation in silicides, fatigue and fracture aspects. A special chapter is given on deformation in silicides in the nano scale. Composites and alloys are also considered.

Joshua Pelleg received his B.Sc. in Chemical Engineering at the Technion-Institute of Technology, Haifa, Israel? a M.Sc. in Metallurgy at the Illinois Institute of Technology, Chicago, IL and a Ph.D. in Metallurgy at the University of Wisconsin, Madison, WI. He has been in the BenGurion University of the Negev (BGU) Materials Engineering Department in BeerSheva, Israel since 1970, and was among the founders of the department, and served as its second chairman. Professor Pelleg was the recipient of the Samuel Ayrton Chair in Metallurgy. He specializes in the mechanical properties of materials and the diffusion and defects in solids. He has chaired several university committees and served four terms as the Chairman of Advanced Studies at BenGurion University of the Negev. Prior to his work at BGU, Pelleg acted as Assistant Professor and then Associate Professor in the Department of Materials and Metallurgy at the University of Kansas, Lawrence, KS. Professor Pelleg was also a Visiting Professor: in the Department of Metallurgy at Iowa State University? at the Institute for Atomic Research, US Atomic Energy Commission, Ames, IA? at McGill University, Montreal, QC? at the Tokyo Institute of Technology, Applied Electronics Department, Yokohama, Japan? and in Curtin University, Department of Physics, Perth, Australia. His nonacademic research and industrial experience includes: Chief Metallurgist in Urdan Metallurgical Works Ltd., Netanyah, Israel? Research Engineer in International Harvester Manufacturing Research, Chicago, IL? Associate Research Officer for the National Research Council of Canada, Structures and Materials, National Aeronautical Establishment, Ottawa, ON? Physics Senior Research Scientist, Nuclear Research Center, BeerSheva, Israel? Materials Science Division, Argonne National Labs, Argonne, IL? Atomic Energy ofCanada, Chalk River, ON? Visiting Scientist, CSIR, National Accelerator Centre, Van de Graaf Group Faure, South Africa? Bell Laboratories, Murray Hill, NJ? and GTE Laboratories, Waltham, MA. His current research interests are diffusion in solids, thin film deposition and properties (mostly by sputtering) and the characterization of thin films, among them various silicides.

Preface8
Contents10
About the Author14
1 What Are the Silicides?16
Reference18
2 Structure19
References26
3 Fabrication27
3.1 Bulk Silicides27
3.1.1 Arc Casting (Melting)27
3.1.2 Directional Solidification28
3.2 Thin Films29
3.2.1 Sputtering29
3.2.2 Electron Beam Deposition30
4 Testing-Deformation31
4.1 Introduction31
4.2 Tension32
4.2.1 CoSi232
4.2.2 NiSi234
4.2.3 MoSi235
4.2.4 WSi2 Film36
4.2.5 FeSi2 Film39
4.2.6 TiSi240
4.3 Compression42
4.3.1 Introduction42
4.3.2 CoSi243
4.3.3 MoSi245
4.3.4 WSi257
4.3.5 TiSi259
4.4 Indentation—Hardness68
4.4.1 Introduction68
4.4.2 NiSi2 Film70
4.4.3 MoSi2 Single Crystal72
4.4.4 WSi2 Film (Coating)76
4.4.5 ?-FeSi277
4.4.6 TiSi279
References82
5 Dislocations in Silicides83
5.1 Introduction83
5.2 Dislocations in CoSi284
5.2.1 Single Crystals84
5.2.2 Film-Single Crystal Epitaxy90
5.3 Dislocations in NiSi294
5.3.1 Epitaxial Thin Film94
5.4 Dislocations in MoSi297
5.4.1 Single Crystals97
5.5 Dislocations in WSi2107
5.5.1 Single Crystals107
5.6 Dislocations in TiSi2111
5.6.1 Single Crystals111
References118
6 Time Dependent Deformation—Creep in Silicides120
6.1 Fundamentals of Creep120
6.2 Creep in CoSi2122
6.3 Creep in MoSi2123
6.4 Creep in MoSi2-WSi2131
6.5 Creep in TiSi2132
References135
7 Fatigue in Silicide Composites136
7.1 Basics136
7.2 Silicide Composites138
7.2.1 Fatigue in MoSi2 Composite138
References151
8 Fracture in Silicides152
8.1 Fracture in CoSi2 Single Crystals152
8.2 Fracture in Polycrystalline CoSi2154
8.3 Fracture in MoSi2 Single Crystals155
8.4 Fracture in Polycrystalline MoSi2158
8.5 Fracture in WSi2 Single Crystals162
8.6 Fracture in Polycrystalline TiSi2162
References167
9 Deformation in Nano Silicides168
9.1 Introduction168
9.2 Tension169
9.3 Hardness Tests170
9.3.1 Hardness in MoSi2170
9.3.2 Hardness in Nano FeSi2173
9.3.3 Hardness in Nano TiSi2175
References175
10 The Effect of B176
10.1 Introduction176
10.2 B Effect in CoSi2177
10.3 B Effect in MoSi2179
10.4 B Effect in TiSi2183
References194
11 Silicide Composites195
11.1 Introduction195
11.2 MoSi2 Based Composites195
11.2.1 MoSi2/SiC196
11.2.2 MoSi2/Si3N4196
11.3 MoSi2/Silicide Composite201
11.4 WSi2 Based Composites210
11.5 TiSi2 Based Composites218
References222
12 Alloying in Silicides223
12.1 Introduction223
12.2 Alloying of NiSi2224
12.3 Alloying of MoSi2225
12.3.1 Metallic Element Addition225
12.3.2 Solid Solution Hardening (Softening)227
12.4 Alloying of FeSi2241
12.4.1 Metallic Element Addition241
12.5 Alloying of TiSi2244
12.6 Alloying of Ti5Si3246
References254
13 Grain Size Effect on Mechanical Properties255
13.1 Introduction255
13.2 MoSi2 Static Properties255
13.3 MoSi2 Creep (Time Dependent) Properties258
13.4 Ti5Si3 Static Properties260
13.5 Creep (Time Dependent) Properties263
References265
14 Environmental Effect267
14.1 Introduction267
14.2 CoSi2-Oxidation267
14.3 NiSi2-Oxidation272
14.4 MoSi2-Oxidation273
14.5 WSi2-Oxidation280
14.6 TiSi2-Oxidation282
References284
Index285