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Nanozymes: Next Wave of Artificial Enzymes

:	Xiaoyu Wang, Wenjing Guo, Yihui Hu, Jiangjiexing Wu, Hui Wei
:	Nanozymes: Next Wave of Artificial Enzymes
:	Springer-Verlag
:	9783662530689
:	1
:	CHF 56.80
:

:	Maschinenbau, Fertigungstechnik
:	English

:	127
:	Wasserzeichen/DRM
:	PC/MAC/eReader/Tablet
:	PDF

This book describes the fundamental concepts, the latest developments and the outlook of the field of nanozymes (i.e., the catalytic nanomaterials with enzymatic characteristics). As one of today’s most exciting fields, nanozyme research lies at the interface of chemistry, biology, materials science and nanotechnology. Each of the book’s six chapters explores advances in nanozymes. Following an introduction to the rise of nanozymes research in the course of research on natural enzymes and artificial enzymes in Chapter 1, Chapters 2 through 5 discuss different nanomaterials used to mimic various natural enzymes, from carbon-based and metal-based nanomaterials to metal oxide-based nanomaterials and other nanomaterials. In each of these chapters, the nanomaterials’ enzyme mimetic activities, catalytic mechanisms and key applications are covered. In closing, Chapter 6 addresses the current challenges and outlines further directions for nanozymes. Presenting extensive information on nanozymes and supplemented with a wealth of color illustrations and tables, the book offers an ideal guide for readers from disparate areas, including analytical chemistry, materials science, nanoscience and nanotechnology, biomedical and clinical engineering, environmental science and engineering, green chemistry, and novel catalysis.

	Preface	6
	Contents	8
	Abbreviations	10
	1 Introduction to Nanozymes	12
	Abstract	12
	References	15
	2 Carbon-Based Nanomaterials for Nanozymes	18
	Abstract	18
	2.1 Fullerene and Derivatives	18
	2.1.1 Fullerene and Derivatives as Nuclease Mimics	19
	2.1.2 Fullerene and Derivatives as SOD Mimics	20
	2.1.3 Fullerene Derivatives as Peroxidase Mimics	23
	2.2 Graphene and Derivatives	23
	2.2.1 Graphene and Its Derivatives as Peroxidase Mimics	23
	2.2.2 Decorated Graphene (or Its Derivatives) as Peroxidase Mimics	26
	2.3 Carbon Nanotubes	31
	2.3.1 Carbon Nanotubes as Peroxidase Mimics	31
	2.3.2 Carbon Nanotubes as Other Enzyme Mimics	33
	2.4 Other Carbon-Based Nanomaterials	35
	2.4.1 Other Carbon Nanomaterials as Peroxidase Mimics	35
	2.4.2 Other Carbon Nanomaterials as SOD Mimics	35
	References	36
	3 Metal-Based Nanomaterials for Nanozymes	41
	Abstract	41
	3.1 Metal Nanomaterials with Catalytic Monolayers (Type I)	41
	3.1.1 AuNPs Protected by Alkanethiol with Catalytic Terminal Moieties	42
	3.1.2 AuNPs Protected by Alkanethiol with Non-covalently Assembled Catalytic Moieties	47
	3.1.3 AuNPs Protected by Thiolated Biomolecules	49
	3.2 Metal Nanomaterials with Intrinsic Enzyme Mimicking Activities (Type II)	50
	3.2.1 Metal Nanomaterials as GOx Mimics	50
	3.2.2 Metal Nanomaterials as Multiple Enzyme Mimics	51
	3.2.3 Applications	55
	References	59
	4 Metal Oxide-Based Nanomaterials for Nanozymes	66
	Abstract	66
	4.1 Cerium Oxide	66
	4.1.1 Cerium Oxide as SOD Mimics	67
	4.1.2 Cerium Oxide as Catalase Mimics	73
	4.1.3 Cerium Oxide as Peroxidase Mimics	75
	4.1.4 Cerium Oxide as Oxidase Mimics	75
	4.1.5 Cerium Oxide as Other Mimics	76
	4.2 Iron Oxide	77
	4.2.1 Iron Oxide as Peroxidase Mimics	77
	4.2.2 Iron Oxide as Other Enzyme Mimics	85
	4.3 Other Metal Oxides	87
	4.3.1 Vanadium Oxide as Enzyme Mimics	87
	4.3.2 Cobalt Oxide as Enzyme Mimics	87
	4.3.3 Copper Oxide as Enzyme Mimics	90
	4.3.4 MoO3, TiO2, MnO2, RuO2 as Enzyme Mimics	90
	References	91
	5 Other Nanomaterials for Nanozymes	101
	Abstract	101
	5.1 Prussian Blue	101
	5.2 Metal-Organic Frameworks	103
	5.3 Metal Chalcogenides	105
	5.4 Metal Hydroxides	105
	5.5 Miscellaneous	106
	References	106
	6 Challenges and Perspectives	111
	Abstract	111
	References	113
	Appendix	116
	References	128