| Editorial | 8 |
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| Contents | 12 |
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| Contributors | 14 |
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| Chapter 1: SCIAMACHY - The Need for Atmospheric Research from Space | 18 |
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| 1.1How to Study the Earth´s Atmosphere from Space? | 19 |
| 1.2The Road to SCIAMACHY | 20 |
| 1.3Determining Impacts on the Earth´s Atmosphere | 23 |
| SCIAMACHY´s Goals | 23 |
| The Atmospheric Layers | 24 |
| Anthropogenic Impact on the Earth-Atmosphere System | 26 |
| Tropospheric Chemistry | 26 |
| Greenhouse Gases: Global Warming and Climate Change | 27 |
| The Tropopause Region | 29 |
| Stratospheric Chemistry and Dynamics | 29 |
| Mesospheric Chemistry and Dynamics | 30 |
| 1.4SCIAMACHY´s Past and Beyond Its Future | 31 |
| The Initial Phases | 31 |
| The Next Decades | 32 |
| References | 33 |
| Chapter 2: ENVISAT - SCIAMACHY´s Host | 35 |
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| 2.1ENVISAT Attitude and Orbit | 36 |
| 2.2ENVISAT On-board Resources | 39 |
| 2.3ENVISAT Ground Segment | 40 |
| 2.4ENVISAT Data Products | 40 |
| 2.5Data Access | 43 |
| References | 44 |
| Chapter 3: The Instrument | 45 |
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| 3.1Instrument Concept | 46 |
| 3.2Optical Assembly | 48 |
| Scan Mechanisms and Baffles | 48 |
| Telescope and Spectrometer | 51 |
| Detector Modules | 51 |
| Calibration Unit | 55 |
| Polarisation Measurement Device | 55 |
| Radiator A and Active Thermal Control | 56 |
| Thermal Bus | 57 |
| 3.3Radiant Cooler Assembly | 57 |
| 3.4Electronic Assembly | 58 |
| Instrument Control Unit | 58 |
| Secondary Processors | 59 |
| Modes | 59 |
| 3.5The Making of SCIAMACHY | 59 |
| References | 62 |
| Chapter 4: Instrument Operations | 63 |
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| 4.1Sun and Moon Observation | 64 |
| Sun Occultation | 66 |
| Sub-solar Observations | 66 |
| Moon Occultation | 67 |
| Refraction | 68 |
| 4.2Reference Measurement Orbit | 68 |
| 4.3Mission Scenarios | 69 |
| 4.4Parameter Tables | 70 |
| 4.5Measurement States | 71 |
| State Definition | 71 |
| Nadir and Limb States | 72 |
| Occultation States | 74 |
| Calibration and Monitoring States | 74 |
| 4.6Timelines | 75 |
| Timeline Concept | 75 |
| Timeline Definition | 76 |
| 4.7SCIAMACHY Operations Setup | 76 |
| References | 78 |
| Chapter 5: Calibration and Monitoring | 79 |
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| 5.1On-ground Calibration Philosophy | 79 |
| 5.2The General Calibration Equation | 80 |
| 5.3Detector Corrections | 81 |
| Channels 1-5 (UV-VIS-NIR) | 82 |
| Channels 6-8 (SWIR) | 84 |
| 5.4Wavelength Calibration | 84 |
| 5.5Stray Light | 85 |
| Spectral Stray Light | 85 |
| Spatial Stray Light | 86 |
| 5.6Polarisation | 86 |
| 5.7Radiometric Calibration | 89 |
| 5.8Optical Performance Monitoring | 90 |
| References | 91 |
| Chapter 6: SCIAMACHY In-Orbit Operations and Performance | 92 |
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| 6.1 Commissioning Phase | 92 |
| Engineering Tasks | 93 |
| Measurement Tasks | 94 |
| The SODAP Sequence | 94 |
| The Validation Sequence | 95 |
| 6.2 Routine Operations Phase | 95 |
| Operation Change Requests and Final Flight Configuration | 97 |
| 6.3 Optical Performance | 98 |
| Optical Throughput | 98 |
| Scan Angle Dependence | 100 |
| Light Leak in Channel 7 | 101 |
| Spatial Stray Light in Limb Measurements | 102 |
| 6.4 Thermal Performance | 103 |
| Ice on Detectors 7 and 8 | 103 |
| Decontamination | 103 |
| Active Thermal Control | 104 |
| Thermal Control | 105 |
| 6.5 Line-of-Sight Performance | 108 |
| Scanners | 108 |
| Extra Mispointing | 109 |
| Tangent Height | 109 |
| 6.6 Mission Extension | 110 |
| Orbit Modification | 110 |
| Impact on Instrument Performance | 112 |
| References | 112 |
| Chapter 7: From Radiation Fields to Atmospheric Concentrations - Retrieval of Geophysical Parameters | 113 |
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| 7.1 Radiative Transfer in the Earth´s Atmosphere | 114 |
| 7.2 Nadir Trace Gas Retrieval Schemes | 116 |
| DOAS Retrieval | 116 |
| Modified DOAS Methods | 121 |
| 7.3 Cloud and Aerosol Retrieval | 121 |
| Cloud Parameters | 122 |
| Cloud Fraction (CF) | 123 |
| Cloud Top Height (CTH) | 125 |
| Cloud Geometrical Thickness (CGT) | 125 |
| Cloud Optical Thickness (COT) and Effective Radius (Reff,cld) | 125 |
| Cloud Phase Index (CPI) | 126 |
| Tropospheric Aerosol Parameters | 126 |
| 7.4Surface Parameter Retrieval | 127 |
| Surface Albedo | 127 |
| Land Vegetation | 129 |
| Oceanic Biological Activity | 129 |
| 7.5Inversion Theory | 129 |
| 7.6Application of Inversion Theory to Limb Retrieval | 131 |
| 7.7 Derivation of Tropospheric Information | 133 |
| Reference Sector Method | 134 |
| Limb/Nadir Matching | 134 |
| Data Assimilation - The NO2 Example | 137 |
| References | 137 |
| Chapter 8: Data Processing and Products | 142 |
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| 8.1Operational Processing Overview | 143 |
| Level 1b Product | 143 |
| Level 1c Product | 144 |
| Level 2 Product | 144 |
| Processing Chains | 144 |
| 8.2Operational Level 0-1b Processing | 146 |
| Memory Effect and Non-linearity | 146 |
| Dark Signal | 146 |
| Pixel-to-Pixel Gain and Etalon | 148 |
| Dead and Bad Pixel Mask | 149 |
| Spectral Stray Light | 149 |
| Wavelength Calibration | 150 |
| Polarisation | 151 |
| Radiometric Correction | 151 |
| Sun Mean Reference Spectrum | 152 |