| Preface | 6 |
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| Contents | 8 |
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| Part I:Principles of Transport,Deposition and Uptake | 10 |
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| Plant Uptake of Xenobiotics | 11 |
| Introduction | 11 |
| Root Uptake | 12 |
| Soil-Root Interactions | 12 |
| Transfer from Roots to Other Plant Parts | 14 |
| Soil-Root Interactions for Ionic Chemicals | 15 |
| Leaf Uptake | 16 |
| Vapour or Gas Uptake from Ambient Air | 16 |
| Particulate Deposition on Plant Surfaces | 17 |
| Other Factors Controlling Plant Uptake of Organic Chemicals | 18 |
| Accumulating Species | 19 |
| Lipid Composition | 19 |
| Foliage | 19 |
| Plant Metabolism | 20 |
| Growth Dilution | 20 |
| Conclusion | 21 |
| References | 21 |
| Haloorganics in Temperate Forest Ecosystems: Sources, Transport and Degradation | 25 |
| Introduction | 26 |
| Sources | 27 |
| Sea Salt | 27 |
| Erosion and Weathering | 28 |
| Fires | 28 |
| Volcanoes | 28 |
| Other Natural Abiotic Sources | 29 |
| Production by Organisms | 29 |
| Intentional Biotic Production | 30 |
| Antibiotics | 30 |
| The Role of Chlorinated Organic Compounds in Microbial Metabolism | 31 |
| Unintentional Biotic Production | 32 |
| De-icing Salt | 33 |
| Other Anthropogenic Sources | 33 |
| Transport Within the Ecosystem | 34 |
| Leaching | 35 |
| Volatilisation | 36 |
| Role of Fire | 38 |
| Plant Litter | 38 |
| Degradation | 39 |
| Abiotic Degradation | 39 |
| Biotic Degradation | 39 |
| Site Budgets | 44 |
| Gaps in Knowledge | 45 |
| References | 46 |
| Semivolatiles in the Forest Environment: The Case of PAHs | 54 |
| Introduction to Polycyclic Aromatic Hydrocarbons | 54 |
| Properties of PAHs | 56 |
| Sources of PAHs | 58 |
| Spatial Patterns and Trends of PAH Emissions and Advection | 59 |
| The Fate of PAHs in Forests | 63 |
| Interaction of Air Masses with the Forest Canopy | 65 |
| Deposition of PAHs | 65 |
| Levels of PAHs in Leaves and Needles | 68 |
| PAHs in the Litter and the Soil | 70 |
| Deposition of PAHs | 70 |
| Levels of PAHs in Soils | 72 |
| Effects of PAHs on Ecosystems | 74 |
| References | 77 |
| Part II:Case Studies | 81 |
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| A Case Study: Uptake and Accumulation of Persistent Organic Pollutants in Cucurbitaceae Species | 82 |
| Introduction | 82 |
| The Cucurbitaceae Family | 84 |
| POPs and Cucurbita Species | 85 |
| DDT/DDE/DDD | 85 |
| Dieldrin and Endrin | 85 |
| Heptachlor | 86 |
| Chlordane | 86 |
| Polychlorinated Biphenyls | 86 |
| Dioxins and Furans | 87 |
| Conclusions | 87 |
| References | 88 |
| Trichloroacetic Acid in the Forest Ecosystem | 91 |
| Introduction | 91 |
| Properties of Trichloroacetic Acid and Its Occurrence in the Environment | 92 |
| Plants and TCA | 93 |
| Physiological Effects | 96 |
| The Role of the Rhizosphere | 99 |
| Conclusions | 101 |
| References | 102 |
| Persistent Organic Pollutants (POPs) in Switzerland Related to Long-Range Transboundary Transport – Results of a Case Study with Special Emphasis on the Spatial Distribution of Polycyclic Aromatic and Chlorinated Air Borne Pollutants | 108 |
| Introduction | 109 |
| Material and Methods | 109 |
| Results and Discussion | 111 |
| Short Chain Chlorinated Paraffin’s (CFCs) | 111 |
| Chlorobenzenes | 111 |
| Hexachlorocyclohexanes (HCH) | 111 |
| Organochlorine Pesticides (OCPs) | 111 |
| Polychlorinated Biphenyls (PCBs) | 117 |
| Polychlorinated Dibenzo-p-Dioxins and Furans (PCDDs/PCDFs) | 117 |
| Polycyclic Aromatic Hydrocarbons (PAHs) | 120 |
| Conclusion | 121 |
| References | 123 |
| Part III:Pollutant Degradationand Ecosystem Remediation fromEnzymes to Whole Plants | 125 |
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| New Perspectives on the Metabolism and Detoxification of Synthetic Compounds in Plants | 126 |
| Introduction | 126 |
| The Plant Xenome and Its Organization | 128 |
| Detoxifying Enzymes | 130 |
| Phase 1 Enzymes – Oxido-Reductases | 130 |
| Phase 1 Enzymes – Hydrolases | 132 |
| Phase 2 Enzymes – Glutathione Transferases (Gsts) | 133 |
| Phase 2 Enzymes – Glycosyltransferases | 136 |
| Phase 2 Enzymes – Malonyltransferases | 138 |
| Phase 3 Transport Processes – ABC Transporter Proteins | 139 |
| Phase 4 – Further Processing of Xenobiotics | 140 |
| Up-Regulation of the Xenome and Xenobiotic Resistance | 142 |
| Conclusion | 144 |
| References | 144 |
| Using Plants to Remove Foreign Compounds from Contaminated Water and Soil | 150 |
| Introduction | 151 |
| Phytoremediation of Organics | 151 |
| Selection of Plants for Phytoremediation | 151 |
| The Applicability of Phytoremediation | 152 |
| Sulphonated Aromatic Compounds in Wastewater | 154 |
| Limits of Microbial Degradability | 155 |
| Potential of Phytotreatment | 156 |
| Azo Dyes in Industrial Effluents | 161 |
| Conventional Dye Treatments | 166 |
| Azo-Dyes Phytoremediation | 167 |
| Rhizodegradation | 168 |
| Phytodegradation | 168 |
| Hydrophobic Compounds: Phytoremediation of PCB-Contaminated Soils | 172 |
| Phytoextraction | 175 |
| Phytodegradation | 176 |
| Rhizoremediation | 177 |
| Bioaugmentation by Rhizosphere Colonising Strains | 178 |
| Use of Activated Carbon | 179 |