: Peter Schröder, Christopher D. Collins
: Peter Schröder, Christopher D. Collins
: Organic Xenobiotics and Plants From Mode of Action to Ecophysiology
: Springer-Verlag
: 9789048198528
: 1
: CHF 133.00
:
: Botanik
: English
: 311
: Wasserzeichen/DRM
: PC/MAC/eReader/Tablet
: PDF
Natural and agro-ecosystems are frequently exposed to natural or synthetic substances, which, while they have no direct nutritional value or significance in metabolism, may negatively affect plant functioning. These, xenobiotics, may originate from both natural (fires, volcano eruptions, soil or rock erosion, biodegradation) and anthropogenic (air and soil pollution, herbicides) sources. And, while affected plants have only a limited number of possibilities for avoiding accumulation of these compounds, they do exhibit several enzymatic reactions for detoxification including oxidation, reduction, hydrolysis and conjugation reactions. In agro-ecosystems in particular these mechanisms have great significance in relation to herbicide detoxification and tolerance. In this volume an international group of experts present an overview of the nature and distribution of organic xenobiotics, including their uptake, effects on plant functioning and detoxification mechanisms. The particular significance of glutathione S-transferases in bio-indication and bio-monitoring, and in the detoxification of volatile organic air pollutants and herbicides is evaluated, and their potential significance in phytoremediation and bioaccumulation will be discussed. This volume will be of interest to a wide audience, from graduate students to senior researchers in a wide range of disciplines including plant ecology, plant biochemistry, agriculture and environmental management. It will also be of practical interest to environmentalists, policy makers and resource managers.
Preface6
Contents8
Part I:Principles of Transport,Deposition and Uptake10
Plant Uptake of Xenobiotics11
Introduction11
Root Uptake12
Soil-Root Interactions12
Transfer from Roots to Other Plant Parts14
Soil-Root Interactions for Ionic Chemicals15
Leaf Uptake16
Vapour or Gas Uptake from Ambient Air16
Particulate Deposition on Plant Surfaces17
Other Factors Controlling Plant Uptake of Organic Chemicals18
Accumulating Species19
Lipid Composition19
Foliage19
Plant Metabolism20
Growth Dilution20
Conclusion21
References21
Haloorganics in Temperate Forest Ecosystems: Sources, Transport and Degradation25
Introduction26
Sources27
Sea Salt27
Erosion and Weathering28
Fires28
Volcanoes28
Other Natural Abiotic Sources29
Production by Organisms29
Intentional Biotic Production30
Antibiotics30
The Role of Chlorinated Organic Compounds in Microbial Metabolism31
Unintentional Biotic Production32
De-icing Salt33
Other Anthropogenic Sources33
Transport Within the Ecosystem34
Leaching35
Volatilisation36
Role of Fire38
Plant Litter38
Degradation39
Abiotic Degradation39
Biotic Degradation39
Site Budgets44
Gaps in Knowledge45
References46
Semivolatiles in the Forest Environment: The Case of PAHs54
Introduction to Polycyclic Aromatic Hydrocarbons54
Properties of PAHs56
Sources of PAHs58
Spatial Patterns and Trends of PAH Emissions and Advection59
The Fate of PAHs in Forests63
Interaction of Air Masses with the Forest Canopy65
Deposition of PAHs65
Levels of PAHs in Leaves and Needles68
PAHs in the Litter and the Soil70
Deposition of PAHs70
Levels of PAHs in Soils72
Effects of PAHs on Ecosystems74
References77
Part II:Case Studies81
A Case Study: Uptake and Accumulation of Persistent Organic Pollutants in Cucurbitaceae Species82
Introduction82
The Cucurbitaceae Family84
POPs and Cucurbita Species85
DDT/DDE/DDD85
Dieldrin and Endrin85
Heptachlor86
Chlordane86
Polychlorinated Biphenyls86
Dioxins and Furans87
Conclusions87
References88
Trichloroacetic Acid in the Forest Ecosystem91
Introduction91
Properties of Trichloroacetic Acid and Its Occurrence in the Environment92
Plants and TCA93
Physiological Effects96
The Role of the Rhizosphere99
Conclusions101
References102
Persistent Organic Pollutants (POPs) in Switzerland Related to Long-Range Transboundary Transport – Results of a Case Study with Special Emphasis on the Spatial Distribution of Polycyclic Aromatic and Chlorinated Air Borne Pollutants108
Introduction109
Material and Methods109
Results and Discussion111
Short Chain Chlorinated Paraffin’s (CFCs)111
Chlorobenzenes111
Hexachlorocyclohexanes (HCH)111
Organochlorine Pesticides (OCPs)111
Polychlorinated Biphenyls (PCBs)117
Polychlorinated Dibenzo-p-Dioxins and Furans (PCDDs/PCDFs)117
Polycyclic Aromatic Hydrocarbons (PAHs)120
Conclusion121
References123
Part III:Pollutant Degradationand Ecosystem Remediation fromEnzymes to Whole Plants125
New Perspectives on the Metabolism and Detoxification of Synthetic Compounds in Plants126
Introduction126
The Plant Xenome and Its Organization128
Detoxifying Enzymes130
Phase 1 Enzymes – Oxido-Reductases130
Phase 1 Enzymes – Hydrolases132
Phase 2 Enzymes – Glutathione Transferases (Gsts)133
Phase 2 Enzymes – Glycosyltransferases136
Phase 2 Enzymes – Malonyltransferases138
Phase 3 Transport Processes – ABC Transporter Proteins139
Phase 4 – Further Processing of Xenobiotics140
Up-Regulation of the Xenome and Xenobiotic Resistance142
Conclusion144
References144
Using Plants to Remove Foreign Compounds from Contaminated Water and Soil150
Introduction151
Phytoremediation of Organics151
Selection of Plants for Phytoremediation151
The Applicability of Phytoremediation152
Sulphonated Aromatic Compounds in Wastewater154
Limits of Microbial Degradability155
Potential of Phytotreatment156
Azo Dyes in Industrial Effluents161
Conventional Dye Treatments166
Azo-Dyes Phytoremediation167
Rhizodegradation168
Phytodegradation168
Hydrophobic Compounds: Phytoremediation of PCB-Contaminated Soils172
Phytoextraction175
Phytodegradation176
Rhizoremediation177
Bioaugmentation by Rhizosphere Colonising Strains178
Use of Activated Carbon179