| Preface | 6 |
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| Contents | 8 |
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| Modern Physics of Ferroelectrics: Essential Background | 14 |
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| 1 Introduction | 14 |
| 2 Switching and Hysteresis Loops | 15 |
| 3 Crystallographic Signature of Ferroelectricity | 19 |
| 4 Materials | 21 |
| 5 Applications of Ferroelectric Materials | 33 |
| 6 Note from the Editors | 36 |
| References | 36 |
| Index | 42 |
| Theory of Polarization: A Modern Approach | 44 |
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| 1 Why is a Modern Approach Needed? | 44 |
| 2 Polarization as an Adiabatic Flow of Current | 49 |
| 3 Formal Description of the Berry-Phase Theory | 54 |
| 4 Implications for Ferroelectrics | 65 |
| 5 Further Theoretical Developments | 70 |
| 6 Summary | 77 |
| References | 78 |
| Index | 80 |
| A Landau Primer for Ferroelectrics | 82 |
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| 1 Introduction | 82 |
| 2 Landau–Devonshire Theory | 87 |
| 3 Landau–Ginzburg Theory | 97 |
| 4 Reduced Size and Other Boundary Effects | 105 |
| 5 Summary and (Some) Open Questions | 117 |
| References | 119 |
| Index | 128 |
| First-Principles Studies of Ferroelectric Oxides | 129 |
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| 1 Introduction | 129 |
| 2 First-Principles Methods | 130 |
| 3 Results for Perovskite Oxide Compounds | 135 |
| 4 Results for Other Ferroelectric Oxide Compounds | 155 |
| 5 Results for Solid Solutions | 158 |
| 6 Results for Defects | 162 |
| 7 Results for Surfaces, Thin Films, Superlattices, Nanowires and Nanoparticles | 164 |
| 8 Challenges and Prospects | 166 |
| References | 168 |
| Index | 185 |
| Analogies and Differences between Ferroelectrics and Ferromagnets | 188 |
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| 1 Fundamentals | 190 |
| 2 Applications | 207 |
| 3 Multiferroics | 211 |
| 4 Outlook | 223 |
| References | 224 |
| Index | 229 |
| Growth and Novel Applications of Epitaxial Oxide Thin Films | 231 |
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| 1 Introduction | 231 |
| 2 Thin-Film Growth of Complex Oxides | 233 |
| 3 Substrates | 269 |
| 4 Applications of Epitaxial Oxide Thin Films | 281 |
| References | 302 |
| Index | 316 |
| Ferroelectric Size Effects | 317 |
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| 1 Size Effects in Ferroelectrics | 317 |
| 2 Size Effects in the Ginzburg–Landau–Devonshire Theory | 318 |
| 3 Extrinsic Size Effects | 319 |
| 4 Effect of Screening | 320 |
| 5 Superlattices | 336 |
| 6 Other Geometries | 338 |
| References | 342 |
| Index | 349 |
| Nanoscale Studies of Domain Walls in Epitaxial Ferroelectric Thin Films | 350 |
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| 1 Introduction | 350 |
| 2 Ferroelectric Domain Walls as Elastic Disordered Systems | 351 |
| 3 Static and Dynamic Behavior of Elastic Disordered Systems | 352 |
| 4 Experimental Observation of Domain-Wall Creep | 355 |
| 5 Domain-Wall Creep in a Commensurate Potential | 358 |
| 6 Domain-Wall Creep in a Random Potential | 362 |
| 7 Experimental Observation of Domain-Wall Roughness | 365 |
| 8 Domain Walls in the Presence of Random- Bond Disorder and Dipolar Interactions | 368 |
| 9 Recent Studies of Ferroelectric Domain-Wall Dynamics | 369 |
| 10 Conclusions | 370 |
| References | 371 |
| Index | 373 |
| APPENDIX A – Landau Free- Energy Coefficients | 374 |
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| Appendix B – Material– Substrate Combinations Tables | 383 |