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Mesoporous Organic-Inorganic Non-Siliceous Hybrid Materials Basic Principles and Promising Multifunctionality

:	Yun-Pei Zhu, Zhong-Yong Yuan
:	Mesoporous Organic-Inorganic Non-Siliceous Hybrid Materials Basic Principles and Promising Multifunctionality
:	Springer-Verlag
:	9783662456347
:	1
:	CHF 49.80
:

:	Anorganische Chemie
:	English

:	127
:	Wasserzeichen/DRM
:	PC/MAC/eReader/Tablet
:	PDF

This book provides extensive information on organic-inorganic hybrid materials with controllable compositions and structures developed over the past few decades, including metal sulfonates, carboxylates, phosphonates, metal-organic frameworks (MOFs), etc. A variety of judicious strategies for optimizing mesoporosity are also introduced, aiming at realizing the corresponding superiorities of hybrid frameworks in practical applications at the nano-/meso-scale. The morphological design and modification methods are also described in detail, which extend the potential application range of hybrid materials from traditional areas to high-tech fields.
The book offers an ideal reference work for readers in the fields of chemistry, chemical engineering, physics, materials and biology, especially those who are interested in porous hybrid materials.

Zhong-Yon Yuan is a Chair Professor at the College of Chemistry, Nankai University, China.

Yun-Pei Zhu received his BSc degree in 2011 at Henan Polytechnic University. He is currently a PhD candidate in Physical Chemistry under the supervision of Prof. Zhong-Yong Yuan at Nankai University. His current research relates to the rational design of porous organic-inorganic hybrid materials for applications in catalysis, adsorption/separation, biosensing and photoelectrochemistry.

Pro . Zhong-Yong Yuan received his BSc degree from Zhejiang Normal University in 1990, and obtained his MSc and PhD degrees from Nankai University in 1996 and 1999, respectively. After his postdoctoral research at the Institute of Physics, Chinese Academy of Sciences, he joined the Laboratory of Inorganic Materials Chemistry at the University of Namur, Belgium in 2001. In 2005, he was appointed as a Chair Professor at Nankai University. In 2006, he was awarded the 'Program for New Century Excellent Talents in University' by the Ministry of Education, China. His research interests are mainly focused on the self-assembly of hierarchically nanoporous and nanostructured materials for energy and environmental applications. He has co-authored more than 190 publications in prestigious journals and 3 book chapters, and holds 10 patents.

	Preface	6
	Contents	8
	1 Introduction	10
	Abstract	10
	References	13
	2 History and Classification of Non-Siliceous Hybrid Materials	16
	Abstract	16
	2.1 Brief History of Hybrid Materials	16
	2.2 Classification of Non-Siliceous Hybrid Materials	20
	2.3 General Strategies of Incorporating Organic Groups	25
	2.3.1 Surface Functionalization	25
	2.3.2 Direct Synthesis	27
	References	28
	3 Strategies to Incorporate Mesoporosity	33
	Abstract	33
	3.1 Template-Free Self-assembly Synthesis Strategy	34
	3.1.1 Ligand Extension	36
	3.1.2 Microemulsion Method	38
	3.1.3 Nanocrystal Self-assembly	39
	3.2 Surfactant-Mediated Synthesis Strategy	43
	3.2.1 Synthesis Mechanism	45
	3.2.2 How to Effectively Obtain Periodic Mesoporosity	46
	3.2.3 Mesostructure Design	54
	3.2.4 Pore Size Control	56
	3.2.5 Improving the Crystallization of Pore Walls	59
	References	63
	4 Morphological Design of Mesoporous Hybrid Materials	68
	Abstract	68
	4.1 Spheres and Fibers	68
	4.2 Nanoplates and Films	72
	4.3 Nanorods	74
	4.4 Monoliths	76
	References	79
	5 Modification and Potential Applications of Organic–Inorganic Non-Siliceous Hybrid Materials	81
	Abstract	81
	5.1 Multiphase Adsorption and Separation	82
	5.1.1 Gas Adsorption	82
	5.1.2 Liquid Adsorption and Separation	84
	5.2 Energy Conversion and Storage	88
	5.2.1 Photocatalysis	88
	5.2.2 Photoelectrochemical Conversion	92
	5.2.3 Potential Fuel Cell Applications	96
	5.3 Heterogeneous Catalysis	100
	5.3.1 Pure Hybrid Framework	100
	5.3.2 Post-functionalization for Catalysis	105
	5.4 Biomaterials	109
	5.4.1 Biomolecule Adsorption and Separation	109
	5.4.2 Drug Delivery	111
	5.4.3 Biosensors	113
	References	118
	6 Summary and Outlook	125
	Abstract	125